Jayaraj Nithyanandhan

Jayaraj Nithyanandhan

Physical and Materials Chemistry Division

About Me

Our research interests are broadly in studying photo initiated processes in organic and materials chemistry.  We are particularly interested in synthesizing metal free organic dyes for dye sensitized solar cells, photo activated methods for processing organic molecules for organic electronics and solar cells.  

Professional Experience

2012 – present: Scientist, CSIR-National Chemical Laboratory, Pune.

2006 – 2011: Post-Doctoral Associate, University of Miami, Coral Gables, FL33146, USA (Mentor: Professor V. Ramamurthy)

2000 – 2006 : Ph. D., Organic Chemistry, Indian Institute of Science, Bangalore (Mentor: Professor N. Jayaraman).

 

1.        Panchromatic sensitizer for dye-sensitized solar cells: Un-symmetrical squaraine dyes incorporating benzodithiophene p-spacer with alkyl chains to extend conjugation, control the dye assembly on TiO2 and retard charge recombination, Bisht, R.; Munavvar M. M. K.; Singh, A. K.; Nithyanandhan, J.  J. Org. Chem. 2017, Manuscript accepted (DOI:10.1021/acs.joc.6b02670).

2.        Effect of out-of-plane alkyl group’s position in dye sensitized solar cell efficiency:  A structure-property relationship utilizing indoline based unsymmetrical squaraine dyes, Ananthan, A.; Munavvar, F. M. K.; Punitharasu, V.; Sil, M. C.; Nithyanandhan, J. ACS Applied Mater. Interfaces, 2016, 8, 35353–35367 (DOI: 10.1021/acsami.6b12730).

3.      Heterotriangulene-based unsymmetrical squaraine dyes: synergistic effects of donor moieties and outof-plane branched alkyl chains on dye cell performance, Karjule, N.; Munavvar, F. M. K.; Nithyanandhan, J. J. Mater. Chem. A, 2016, 4, 18910-18921.

(Selected for themed collection of 2016 Journal of Materials Chemistry A HOT Papers)

4.   A dendrimer facilitates resonance energy transfer between hydrophobic aromatic guest molecules in water, Singh, Y.; Raj, A. M.; Kiran, B. M.; Nithyanandhan, J.; Ramamurthy, V.; Jayaraman, N. J. Photochem. Photobiol A Chem. 2016, 317, 125–131.

5.      Release of a Guest by Disassembling a Capsule Through a Photo triggering Process, Jayaraj, N.; , Jagadesan, P.; Samanta, S. R.; Da Silva, J. P.; V. Ramamurthy, Org. Lett. 2013, 15, 4374-4377.

 

Selected Publications

  • Punitharasu V, Mele Kavungathodi M F, Singh A K And Nithyanandhan J, pi-Extended cis-Configured Unsymmetrical Squaraine Dyes for Dye-sensitized Solar Cells: Panchromatic Response, ACS Appl. Energy Mater., 2, 8464 - 8472 (2019), DOI:10.1021/acsaem.9b01341.
  • Bisht R, Kavungathodi M F M And Nithyanandhan J, Indenoquinaldine Based Unsymmetrical Squaraine Dyes for Near-Infrared Absorption: Investigating the Steric and Electronic Effects in Dye-Sensitized Solar Cells, Chem. Eur. J., 24, 16368 - 16378 (2018), DOI:10.1002/chem.201803062.
  • Punitharasu V, Mele Kavungathodi M F And Nithyanandhan J, Interplay between pi-Bridges and Positions of Branched Alkyl Groups of Unsymmetrical D–A–D-pi spacer–A Squaraines in Dye-Sensitized Solar Cells: Mode of Dye Anchoring and the Charge Transfer Process at the TiO2/Dye/Electrolyte Interface, ACS Applied Materials and Interfaces., 9, 32698 - 32712 (2017), DOI:10.1021/acsami.7b08346.
  • Bisht, R.; Munavvar M. M. K.; Singh, A. K.; Nithyanandhan And J, Panchromatic sensitizer for dye-sensitized solar cells: Un-symmetrical squaraine dyes incorporating benzodithiophene pi-spacer with alkyl chains to extend conjugation, control the dye assembly on TiO2 and retard charge recombination, J. Org. Chem., 82, 1920 - 1930 (2017), DOI:10.1021/acs.joc.6b02670.
  • Karjule N, Mele Kavungathodi M F And Nithyanandhan J, Heterotriangulene-based unsymmetrical squaraine dyes: synergistic effects of donor moieties and outof-plane branched alkyl chains on dye cell performance, J. Mater. Chem. A., 4, 18910 - 18921 (2016), DOI:10.1039/C6TA08651A.
    (Selected for themed collection of 2016 Journal of Materials Chemistry A HOT Papers)

Research Interest

  • Materials Chemistry
  • Organic electronic devices
  • Supramolecular Chemistry
  • Photoinduced processes

Contact Details

J. Nithyanandhan, Ph.D.
Scientist, Physical & Materials Chemistry Division
F-102 Polymers & Advanced Materials Laboratory
CSIR-National Chemical Laboratory
Dr. Homi Bhabha Road, Pune - 411 008
Maharashtra, INDIA

Phone : +91 020 2590 3050
Fax       : +91 020 2590 2636