Satyadip Paul, Mani Gupta, Kaushik Dey, Ashok Mahato, Saikat Bag, Arun Torris, Bhoje Gowd, Hasnain Sajid, Matthew Addicoat, Supratim Datta And Rahul Banerjee, Hierarchical Covalent Organic Framework-foam for Multienzyme
Tandem Catalysis, Chemical Science., , (2023), DOI:(Just Accepted).
Pillai M And Das A And Jha SK, Electrostatic modulation of intramolecular and intermolecular interactions during the formation of an amyloid-like assembly, Biochemistry., IN PRESS, (2023), DOI:10.1021/acs.biochem.3c00014.
Patni D And Jha SK, Thermodynamic modulation of folding and aggregation energy landscape by DNA binding of functional domains of TDP-43, BBA - Proteins and Proteomics., 1871, 140916 (2023), DOI:10.1016/j.bbapap.2023.140916.
Abdul Khayum Mohammed, Jesus Raya, Ajmal Pandikassala, Matthew A. Addicoat, Safa Gaber, Mohamed Aslam, Liaqat Ali, Sreekumar Kurungot And Dinesh Shetty, Chemically Gradient Hydrogen-Bonded Organic Framework Crystal Film, Angewandte Chemie., Just Accepted Manuscript, (2023), DOI:10.1002/anie.202304313.
Apurva Patrike, Indrapal Karbhal, Kundan Wasnik, Arun Torris, Ashakiran Maibam, Sailaja Krishnamurty And Manjusha V. Shelke*, High Rate, High Temperature, Dendrite Free Plating/Stripping of Li in 3-Dimensional Honeycomb Boron Carbon Nitride to Realize an Ultrastable Lithium Metal Anode, Journal of energy storage., accepted, (2023).
Love Dashairya, Vikash Chaturvedi, Abhishek Kumar, Tandra Rani Mohanta, Manjusha Shelke And Partha Saha , A benign strategy toward mesoporous carbon coated Sb nanoparticles: A high-performance Li-ion/Na-ion batteries anode, Solid State Ionics., 396, 116243 (2023).
Supriya Sahoo, Premkumar Kothavade, Dipti Naphade, Arun Torris, Balu Praveenkumar, Jan Zar?ba, Thomas Anthopoulos, Kadhiravan Shanmuganathan And Ramamoorthy Boomishankar, 3D-printed Polymer Composite Devices Based on a Ferroelectric
Chiral Ammonium Salt for High-Performance Piezoelectric Energy
Harvesting, Materials Horizons., , (2023), DOI:(Just Accepted).
Palak Patel, Mohit Sharma And Sarika Maitra Bhattacharyya, Dynamic heterogeneity in polydisperse systems: A comparative study of the role of local structural order parameter and particle size, arXiv., , (2023), DOI:arXiv:2305.02043.
Jyoti R. Kadam, Tufeil S. Khan And Paresh L. Dhepe, Designing an industrially viable bimetallic catalyst for the polyol synthesis, New Journal of Chemistry., 47, 7548 - 7555 (2023), DOI:10.1039/D3NJ00044C.
Kritika Gour, Gargi Kundu, Soumya Ranjan Dash, Srinu Tothadi, Kumar Vanka And Sakya S. Sen*, Six-Membered NHC Stabilized Monomeric Zinc Complexes, Eur. J. Inorg. Chem., , (2023), DOI:10.1002/ejic.202300167.
Equal contribution from the first two authors
Gargi Kundu, P. R. Amrutha, K. Vipin Raj, Srinu Tothadi, Kumar Vanka And Sakya S. Sen*, Taming the parent oxoborane, Chem. Sci., , (2023), DOI:10.1039/D3SC01544K.
Ashutosh Rana, Anup Thakare, Nikhil Kumar, Buddhadev Mukherjee, Arun Torris, Bidisa Das, Satishchandra Ogale And Abhik Banerjee, Mitigating Dendrite Formation on a Zn Electrode in Aqueous Zinc Chloride by the Competitive Surface Chemistry of an Imidazole Additive (Just Accepted Article), ACS Applied Materials & Interfaces., , (2023), DOI:10.1021/acsami.3c01310.
S. Bansal, R. G. Gonnade And B. Punji, Chemodivergent coupling of azoarenes with benzyl alcohols via borrowing hydrogen strategy using a well-defined nickel catalyst, Catal. Sci. Technol., 13, 2705 - 2713 (2023), DOI:10.1039/d3cy00090g.
Neha, H.K. Sardana, R. Kanawade And N. Dogra , Photoplethysmograph based arrhythmia detection using morphological features, Biomedical Signal Processing and Control., 81, 104422 (2023), DOI:https://doi.org/10.1016/j.bspc.2022.104422.
Shivshankar Kore, Rudhi Ranjan Sahoo, Binit Santra, Archishman Sarkar, Tubai Chowdhury, Samadhan H. Deshmukh, Sulagna Hazarika, Srijan Chatterjee* And Sayan Bagchi*, Solvation structure and dynamics of a small ion in an organic electrolyte, J. Photochem. Photobiol. A., 440, 114666 (2023), DOI:https://doi.org/10.1016/j.jphotochem.2023.114666.
Srijan Chatterjee, Tubai Chowdhury And Sayan Bagchi*, Does variation in composition affect dynamics when approaching the eutectic composition?, J. Chem. Phys., 158, 114203 (2023), DOI:https://doi.org/10.1063/5.0139153.
Apurva Patrike, Indrapal Karbhal, Kundan Wasnik, Arun Torris, Ashakiran Maibam, Sailaja Krishnamurty And Manjusha Shelke, High Rate, High Temperature, Dendrite Free Plating/Stripping of Li in 3-Dimensional Honeycomb Boron Carbon Nitride to Realize an Ultrastable Lithium Metal Anode (Just Accepted), Journal of Energy Storage., , (2023).
Premkumar Kothavade, Prashant Yadav, Aakash Nidhankar, Arun Torris, Harshawardhan Pol, Abdullah Kafi, Stuart Bateman, Santosh Sukumaran And Kadhiravan Shanmuganathan, Luminescent 3D Printed Poly(lactic acid) Nanocomposites with Enhanced Mechanical Properties (Just Accepted), Polymer Engineering & Science., , (2023).
Venkata Ramachandrula, Ramamohan Kasa And Arun Torris, Micro-Computed Tomography (µCT) Study of Clogging in Long-Used Strip and Cylindrical Drip Emitters, Journal of The Institution of Engineers., 104 (1), 167 - 174 (2023), DOI:10.1007/s40030-022-00697-3.
Yogesh Mahajan, Balkrishna Shinde, Arun Torris, Akshay Gade, Vipul Patil, C. K. John, Narendra Kadoo And Tukaram Nikam, Pre-Sowing Treatments, Seed Components and Water Imbibition Aids Seed Germination of Gloriosa superba, Seeds., 2 (1), 15 - 29 (2023), DOI:10.3390/seeds2010002.
Manoj Krishnat Patil, † Supriya Hanmant Gaikwad, † Arun Arunima Balachandran Kirali, Banu Marimuthu* And and Shatabdi Porel Mukherjee* (†Authors contributed equally), Ligand-free one-pot synthesis of Ru@W18O49 self-assembled hierarchical nanostructures for selective conversion of glucose into glycols, ACS Applied Nano Materials (under revision)., , (2023).
Geeta Pandurang Kharabe, Rajith Illathvalappil, Sidharth Barik, Fayis Kanheerampockil, Priyanka S. Walko, Suresh K. Bhat, R. Nandini Devi And Sreekumar Kurungot, Cobalt-Manganese Modified Theophrastite Phase of Nickel Hydroxide Nanoflower Arrays on Nickel Foam as self-standing Bi-functional Electrode for Overall Water Electrolysis, Sustainable Energy & Fuels., Just Accepted Manuscript, (2023), DOI:10.1039/D3SE00233K.
Vidyanand Vijayakumar, Meena Ghosh, Kiran Asokan, Santhosh Babu Sukumaran, Sreekumar Kurungot, Jonas Mindemark, Daniel Brandell, Martin Winter And Jijeesh Ravi Nair, 2D Layered Nanomaterials as Fillers in Polymer Composite Electrolytes for Lithium Batteries, Advanced Energy Materials., Just Accepted Manuscript, (2023), DOI:10.1002/aenm.202203326.
Abdul Khayum Mohammed, Pilar Pena Sánchez, Ajmal Pandikassala, Safa Gaber, Ayesha A. AlKhoori, Tina Skorjanc, Kyriaki Polychronopoulou, Sreekumar Kurungot, Felipe Gándara And Dinesh Shetty , Salicylaldehydate Coordinated Two-Dimensional-Conjugated Metal-Organic Frameworks, Chem. Commun., 59, 2608 - 2611 (2023), DOI:10.1039/D2CC06283F.
Sachin Kumar, Athira Yoyakki, Ajmal Pandikassala, Roby Soni And Sreekumar Kurungot, Pt-Anchored-Zirconium Phosphate Nanoplates as High-Durable Carbon-Free Oxygen Reduction Reaction Electrocatalyst for PEM Fuel Cell Applications, Advanced Sustainable Systems., 7 (2), 2200330 (2023), DOI:10.1002/adsu.202200330.
Kishor V Khopade, Samir H Chikkali And Nagaraju Barsu, Metal-catalyzed plastic depolymerization, Cell Reports Physical Science., 4, 101341 (2023), DOI:doi.org/ 10.1016/j.xcrp.2023.101341.
Doke AA And Jha SK, Shapeshifter TDP-43: Molecular mechanism of structural polymorphism, aggregation, phase separation and their modulators, Biophys. Chem., 295, 106972 (2023).
Pillai M And Jha SK, Multi-step molecular mechanism of amyloid-like aggregation of nucleic acid-binding domain of TDP-43, Proteins: Struct. Funct. Genet., 91, 649 - 664 (2023), DOI:10.1002/prot.26455.
M. Vijaykumar, C. Pradhan, R. G. Gonnade And B. Punji, Palladium-Catalyzed Chemoselective Oxygenation of C(sp2)-H and
C(sp3)-H Bonds in Isatins, Org. Lett., 25, 1862 - 1867 (2023), DOI:10.1021/acs.orglett.3c00342.
C. Pradhan And B. Punji, Advances in the Iron-Catalyzed Direct Functionalizations of Heterocycles, Synlett., 34, 683 - 697 (2023), DOI:10.1055/a-1890-8503.
Bhavana R Shivankar, Chandrodai Pratap Singh And Sailaja Krishnamurty, Chemically modified graphene sheets as potential sensors for organophosphate compounds (pesticide): A DFT study, Applied Surface Science., 619, 156745 (2023), DOI:https://doi.org/10.1016/j.apsusc.2023.156745.
Pragnya Paramita Samal, Chandrodai Pratap Singh And Sailaja Krishnamurty, Expounding lemonal terpenoids as corrosion inhibitors for copper using DFT based calculations, Applied Surface Science., 614, 156066 (2023), DOI:https://doi.org/10.1016/j.apsusc.2022.156066.
Ashakiran Maibam, Sailaja Krishnamurty And Ravichandar Babarao, Electrocatalytic nitrogen reduction on defective graphene modulated from single atom catalyst to aluminium clusters, Applied Surface Science., , 157024 (2023), DOI:https://doi.org/10.1016/j.apsusc.2023.157024.
Aarti Shukla, Gautam Sharma And Sailaja Krishnamurty, Functionalized Mo2BX2 (X= H, OH, O) MBenes as a promising sensor, capturer and storage material for environmentally toxic gases: A case study of 1T and 2H phase, Applied Surface Science., , 156299 (2023), DOI:https://doi.org/10.1016/j.apsusc.2022.156299.
Kishor V. Khopade, Nagaraju Barsu* And Samir H. Chikkali, Metal-Catalyzed Plastic Depolymerization, Cell Reports Physical Science., 4, 101341 - 1-43 (2023), DOI:https://doi.org/10.1016/j.xcrp.2023.101341.
Poonam Yadav, Apurva Patrike, Kundan Wasnik, Vilas Shelke And Manjusha Shelke*, Strategies and practical approaches for stable and high energy density Sodium-ion battery: a step closer to commercialization, Materials Today Sustainability., accepted, (2023), DOI:https://doi.org/10.1016/j.mtsust.2023.100385.
Vikash Chaturvedi, Meenakshi Pawar, M. Thripuranthaka, Rajkiran Shivade And Manjusha V. Shelke*, Novel Carbon encapsulated NiCo2S4 nanoparticles with enhanced
surface mediated charge storage for superior ultracapacitor
electrodes, Chemistry An Asian Journal., , e202300121 (2023), DOI:https://doi.org/10.1002/asia.202300121.
Invited article for Wiley "CSIR Labs Special Collection"
This article also appears in wiley's
Hot Topic: Surfaces and Interfaces
Apurva Patrike, Kundan Wasnik And Manjusha Shelke*, Few layer graphene lithiophilic and sodiophilic diffusion layer on porous stainless steel as lithium and sodium metal anode, Chemistry An Asian Journal., , e202300068 (2023), DOI:https://doi.org/10.1002/asia.202300068.
Invited article for Wiley "CSIR Labs Special Collection"
Indrapal Karbhal, Vikash Chaturvedi, Poonam Yadav, Apurva Patrike And Manjusha V. Shelke*, Template Directed Synthesis of Boron Carbon Nitride Nanotubes (BCN-NTs) and Their Evaluation for Energy Storage Properties, Advanced Materials Interfaces., 10, 2201560 (2023).
This article features in "Hot Topic: Batteries and Supercapacitors"
Poonam Yadav, Vilas Shelke, Apurva Patrike And Manjusha Shelke*, Sodium Based Batteries: Development, Commercialization Journey and New Emerging Chemistries, Oxford Open Materials Science., 3, itac019 (2023).
Invited Review Article
Vrushali H. Jadhav and Sanjay P. Kamble, Conversion of agricultural crop waste into valuable chemicals, Elsevier Book Chapter., , 57 - 86 (2023).
Swapnali P. Kirdant And Shubham R. Bankar & Vrushali H. Jadhav*, Efficient Synthesis of a Monomer for Bioplastic-FDCA Using Glucose-HTC Catalyst and Pinnick Oxidation from HMF & Fructose, Catalysis Letters., , (2023), DOI:10.1007/s10562-023-04308-z.
Vrushali H. Jadhav And G. P. Nayaka, Spent Li-Ion Battery Cathode Based Catalyst Composition For Oxidation Reactions, Provisional Patent no 202311003936., , (2023).
G.K. Patra*, Kantha Rao Bhimala, Ashapurna Marndi, Saikat Chowdhury, Jarjish Rahaman, Sutanu Nandi, Ram Rup Sarkar, K.C. Gouda, K.V. Ramesha, Rajesh P. Barnwal, Siddhartha Raj And Anil Saini, Deep learning methods for scientific and industrial research, In: Venu Govindaraju. Arni S.R. Srinivasa Rao, C.R. Rao (eds) Handbook of Statistics (Deep Learning), Volume 48, Academic Press, Elsevier, USA, Print ISBN 978-0-443-18430-7., 48, 107 - 168 (2023), DOI:10.1016/bs.host.2022.12.002.
Anirudh Murali And Ram Rup Sarkar*, Mechano-immunology in microgravity, Life Sciences in Space Research., In Press, (2023), DOI:10.1016/j.lssr.2023.03.001.
Tanuja Tewari, Rohit Kumar And Samir H. Chikkali*, Iron-Catalyzed Magnesium-Mediated Formal Hydroformylation of Alkynes and Alkenes, ChemCatChem., 15, e202201394 (2023), DOI:10.1002/cctc.202201394.
Himanshu Sharma, Tanuja Tewari, Samir H. Chikkali* And Kumar Vanka*, Computational Insights into the Iron-Catalyzed Magnesium-Mediated Hydroformylation of Alkynes, J. Organomet. Chem., 986, 122621 (2023), DOI:https://doi.org/10.1016/j.jorganchem.2023.122621.
Rohit Kumar, Vishal Sharma, Subhrashis Banerjee, Kumar Vanka And Sakya S. Sen*, Controlled reduction of isocyanates to formamides using monomeric magnesium, Chem. Commun., 59, 2255 - 2258 (2023).
Himanshu Bajpai, Inderjeet Chauhan, Kranti Salgaonkar, Nitin B Mhamane And and Chinnakonda S Gopinath, Biomass Components to H2 and Value Added Products by Sunlight Driven Photocatalysis with Electronically Integrated Au?--TiO2: Concurrent Utilisation of Electrons and Holes, RSC Sustainability., , (2023), DOI:DOI https://doi.org/10.1039/D2SU00145D.
Milan Kumar Bisai, V. S. Ajithkumar, K. Vipin Raj, Kumar Vanka*, Rajesh G. Gonnade* And Sakya S. Sen*, A zwitterionic disilanylium from an unsymmetric disilene, Chem. Commun., 59, 1669 - 1672 (2023).
Equal contribution from the first two authors
Sanjukta Pahar, Gargi Kundu, Christy P. George, Rajesh G. Gonnade And Sakya S. Sen*, Substitution at a Coordinatively Saturated Aluminum Center Stabilized by Imidazolidin-2-imine, Organometallics., 42, 276 - 282 (2023).
Tushar Dubey, Shweta Kishor Sonawane, Mk Chaitanya Mannava, Ashwini K Nangia, Madhura Chandrashekar And Subashchandrabose Chinnathambi, The inhibitory effect of Curcumin-Artemisinin co-amorphous on Tau aggregation and Tau phosphorylation, Colloids Surf B Biointerfaces., , (2023).
Tushar DubeY, Preethi Kushawa, H V Thulasiram, Madhura Chandrashekar And Subashchandrabose Chinnathambi, Bacopa monnieri reduces Tau aggregation and Tau-mediated toxicity in cells, Int J Biol Macromol ., , (2023), DOI:10.1016/j.ijbiomac.2023.123171.
Rashmi Das and Subashchandrabose Chinnathambi*. , Microglia modulate the podosome rearrangements in lamella in response to external Tau aggregates, Under Revision., , (2023).
Rashmi Das and Subashchandrabose Chinnathambi*. , Microglia degrade extracellular Tau oligomers deposit via Purinergic P2Y12-driven podosome formation, Under Review., , (2023).
Smita Eknath Desale and Subashchandrabose Chinnathambi*, Alpha-Linolenic acid-induced podosome formation and spontaneous higher-order assemblies in N9 microglia cell for chemotaxis, Cellular Signaling., , (2023), DOI:Revision.
Kranti N. Salgaonkar, Sandip R. Kale, Naresh Nalajala And Sayana Mansuri and Chinnakonda S. Gopinath, Selective and Generic Photocatalytic Oxidation of Alcohol with Pd-TiO2 Thin Films: Butanols to Butanal/Butanone with Different Morphologies of Pd and 0.5?Pt-Pd Counterparts, Chemistry: An Asian Journal., , (2023), DOI:https://doi.org/10.1002/asia.202201239.
B P Shivamurthy, G P Nayaka* And G Santhosh, Performance Analysis of Regenerated rGO Electrodes from Spent Li-ion Battery Anodes for Secondary Energy Device Applications, Energy and fuels., , (2023), DOI:https://doi.org/10.1021/acs.energyfuels.2c03888 (I. F. 4.6).
Shivshankar Kore, Samadhan H. Deshmukh, Sushil S Sakpal, Srijan Chatterjee, Atanu Das* And Sayan Bagchi*, Elucidation of pH-Induced Protein Structural Changes: A Combined 2D IR and Computational Approach, Biochemistry., 62, 451 - 461 (2023), DOI:https://doi.org/10.1021/acs.biochem.2c00626.
Inderjeet Chauhan, Kshirodra Kumar Patra, Himanshu Bajpai, Kranti Salgaonkar And Nitin B Mhamane and Gopinath S Chinnakonda, Nanostructured Co-doped BiVO4 for Efficient and Sustainable Photoelectrochemical Chlorine Evolution from Simulated Sea-Water, Dalton Transaction., , (2023), DOI:https://doi.org/10.1039/D2DT03369K.
Singh A, Singh A K, Dixit R, Vanka K, Krishnamoorthy K And Nithyanandhan J, Visible-Light Active Unsymmetrical Squaraine Dyes with 1 V of Open-Circuit Voltage For Dye-sensitized Solar Cell, ChemPhotoChem., manuscript accepted, xxxx - xxxx (2023), DOI:10.1002/cptc.202200328.
Dnyaneshwar V. Bodkhe And Samir H. Chikkali*, Ti-Iminocarboxylate Catalyzed Polymerization of Ethylene to Highly Crystalline, Disentangled, Ultrahigh Molecular Weight Polyethylene, Eur. Polym. J., 182, 111725/1- - 8 (2023), DOI:https://doi.org/10.1016/j.eurpolymj.2022.111725.
R. Ghosh, S. Ghosh And A. Das, Understanding the mechanism of amylin aggregation: From identifying crucial segments to tracing dominant sequential events to modeling potential aggregation suppressors, BBA - Proteins Proteom., 1871, 140866 (2023), DOI:https://doi.org/10.1016/j.bbapap.2022.140866.
Niwesh Ojha, Kavita Thakkar, Abhinav Bajpai, Kavita Joshi And Sushant Kumar, Photoinduced CO2 and N2 Reductions on Plasmonically Enabled Gallium Oxide, Journal of Colloid and Interface Science., 629, 654 - 666 (2023), DOI:https://doi.org/10.1016/j.jcis.2022.09.097.
Ag-containing ZnO/?-Ga2O3 semiconductor, which exhibit reduced bandgap, increased light absorption, and hydrophilicity, have been found to be useful for photocatalytic CO2 reduction and N2 fixation by water. The charge-separation is facilitated by the new interfaces and inherent vacancies. The Ag@GaZn demonstrated the highest photocurrent response, about 20- and 2.27-folds that of the Ga and GaZn samples, respectively. CO, CH4, and H2 formed as products for photo-reduction of CO2. Ag@GaZn catalyst exhibited the highest AQY of 0.121% at 400nm (31.2W/m2). Also, Ag@GaZn generated 740 of NH4+ ions, which was about 18-folds higher than Ga sample. In situ DRIFTS for isotopic-labelled 13CO2 and 15N2 reaffirmed the photo-activity of as-synthesized catalysts. Density functional theory provided insight into the relative affinity of different planes of heterostructures towards H2O, CO2 and N2 molecules. The structure-photoactivity rationale behind the intriguing Ag@GaZn sample offers a fundamental insight into the role of plasmonic Ag and design principle of heterostructure with improved photoactivity and stability.
Singh, S.K., Matsagar, B.M. & Dhepe And P.L, Lignocellulosic biomass analysis: acidic lignin recovery, characterisation, and depolymerization, Biomass Conversion and Biorefinery., , (2022), DOI:10.1007/s13399-022-02705-9.
Varchaswal Kashyap, Ajmal Pandikassala, Gourav Singla, Tuhin Suvra Khan*, M. Ali Haider, C. P. Vinod* And Sreekumar Kurungot*, Unravelling the Faradaic Electrochemical Efficiencies over Fe/Co Spinel Metal Oxides using Surface Spectroscopy and Microscopy Techniques, Nanoscale., 14, 15928 - 15941 (2022), DOI:10.1039/D2NR04170G.
Maria Kurian, Meena Ghosh, Vidyanand Vijayakumar, Priyanka Pandinhare Puthiyaveetil, Arun Torris And Sreekumar Kurungot, Influence of Ice Templating on Oxygen Reduction Catalytic Activity of Metal-Free Heteroatom-Doped Mesoporous Carbon Derived from Polypyrrole for Zinc–Air Batteries, Energy Technology., 10 (12), 2200840 (2022), DOI:10.1002/ente.202200840.
Ajmal Pandikassala, Pranav K. Gangadharan, Radhika Nittoor Veedu And Sreekumar Kurungot, Polydopamine-Derived Iron-Doped Hollow Carbon Nanorods as an Efficient Bifunctional Electrocatalyst for Simultaneous Generation of Hydrogen and Electricity, Energy & Fuels., 36, 18, 11245 - 11260 (2022), DOI:10.1021/acs.energyfuels.2c01659.
Bandhana Devi, Rik Rani Koner And Sreekumar Kurungot, Recent advances in the metal-organic framework-based electrocatalysts for trifunctional electrocatalysis, Dalton Transactions., 51, 13573 - 13590 (2022), DOI:10.1039/D2DT01981G.
Narugopal Manna, Santosh K. Singh, Maria Kurian, Arun Torris And Sreekumar Kurungot, Air–Cathode Interface-Engineered Electrocatalyst for Solid-State Rechargeable Zinc–Air Batteries, ACS Applied Energy Materials., 5, 7, 8756 - 8768 (2022), DOI:10.1021/acsaem.2c01266.
Swati Dilwale, Meena Ghosh, Vidyanand Vijayakumar And Sreekumar Kurungot , Electrodeposited Layered Sodium Vanadyl Phosphate (NaxVOPO4nH2O) as Cathode Material for Aqueous Rechargeable Zinc Metal Batteries, ACS Energy & Fuels., 36, 12, 6520 - 6531 (2022), DOI:10.1021/acs.energyfuels.2c00831.
Meena Ghosh*, Sabine Szunerits, Ning Cao, Sreekumar Kurungot* And Rabah Boukherroub*, Single-Step Synthesis of Exfoliated Ti3C2Tx MXene through NaBF4/HCl Etching as Electrode Material for Asymmetric Supercapacitor, ChemistrySelect., 7(19), e202201166 (2022), DOI:10.1002/slct.202201166.
Nagaraju Shilpa, Ajmal Pandikassala, Perayil Krishnaraj, Priyanka S. Walko, R. Nandini Devi And Sreekumar Kurungot, Co–Ni Layered Double Hydroxide for the Electrocatalytic Oxidation of Organic Molecules: An Approach to Lowering the Overall Cell Voltage for the Water Splitting Process, ACS Appl. Mater. Interfaces., 14 (14), 16222 - 16232 (2022), DOI:10.1021/acsami.2c00982.
Geeta Kharabe , Narugopal Manna, Ayasha Nadeema, Santosh K Singh, Shweta Mehta, Aathira Nair, Kavita Joshi* And Sreekumar Kurungot* , Pseudo-Boehmite AlOOH supported NGr Composite-Based Air Electrode for Mechanically Rechargeable Zn-Air Battery Applications, Journal of Materials Chemistry A., 10, 10014 - 10025 (2022), DOI:10.1039/D2TA00546H.
Jyoti Shukla, Rajith Illathvalappil, Sharvan Kumar, Sonam Chorol, Ajmal Pandikassala, Sreekumar Kurungot And Pritam Mukhopadhyay, Synthesis of a Highly Electron-Deficient, Water-Stable, Large Ionic Box: Multielectron Accumulation and Proton Conductivity, Org. Lett., 24, 3038 - 3042 (2022), DOI:10.1021/acs.orglett.2c00993.
Titas Pramanik, Ashish Anand, Ajmal Pandikassala, Rajith Illathvalappil, Sreekumar Kurungot And Tayur N. Guru Row, Enhanced proton conductivity in amino acid based self-assembled non-porous hydrogen-bonded organic frameworks, Chemical Communications., 58, 5972 - 5975 (2022), DOI:10.1039/D2CC00948J.
Shibin Thundiyil, Ajmal Pandikassala, Sreekumar Kurungot And R. Nandini Devi, Tuning of oxygen reduction pathways through structural variation in transition metal-doped Ba2In2O5, ChemElectroChem., 9 (2), e202101163 (2022), DOI:10.1002/celc.202101163R1.
Nikhil S. Samudre, Chandrodai Pratap Singh And Sailaja Krishnamurty, Understanding the thermal stability of a 3d, 4d, and 5d element doped aluminium nanocluster through BOMD simulations, Molecular Simulation., , 1 - 6 (2022), DOI:https://doi.org/10.1080/08927022.2022.2153151.
Ashakiran Maibam, Babarao Ravichande And Sailaja Krishnamurty, Doped 2D VX2 (X= S, Se, Te) monolayers as electrocatalysts for ammonia production: A DFT based study, Applied Surface Science., 602, 154401 - 154405 (2022), DOI:https://doi.org/10.1016/j.apsusc.2022.154401.
Chandrodai Pratap Singh And Sailaja Krishnamurty, Synergetic storage of ammonia over Al quantum dots embedded graphene sheets: A first principles perspective, International Journal of Hydrogen Energy., 47, 36873 - 36885 (2022), DOI:https://doi.org/10.1016/j.ijhydene.2022.08.268.
Poonam Yadav, Golu Parte, Wahid Malik, Ylias M. Sabri, Lathe A. Jones And Manjusha V. Shelke*, Sustainable composite of SnFe2O4 conversion alloying anode for lithium-ion storage, Sustainable Energy & Fuels., 6, 3806 - 3817 (2022).
Ashvini B. Deshmukh†, Madan R. Biradar†, Meenakshi D. Pawar, Sidhanath V. Bhosale* And Manjusha V. Shelke*, Flexible ultracapacitor device fabricated with an organic electrode material- naphthalene diimide nitrile/reduced graphene oxide, Journal of Energy Storage., 56, 106036 (2022).
Bogalera Papaiah Shivamurthy, Marulasiddappa Thripuranthaka, Manjusha V. Shelke And Girish Praveen Nayaka*, Formation of the Secondary Phase Domain by Multi-Cation Substitution for the Superior Electrochemical Performance of Spinel Cathodes for High-Voltage Li-Ion Batteries, ACS Appl. Energy Mater., 5, 15345 - 15355 (2022).
Kundan Wasnik, Meenakshi Pawar, Leya Rose Raphael, Abhilash Pullanchiyodan, Manjusha Shelke* And Prasanth Raghavan*, MXenes: Advances in the Synthesis and Application in Supercapacitors and Batteries, Journal of Materials Research., 37, 3865 - 388 (2022).
Prasanth Raghavan, Jou-Hyeon Ahn And Manjusha Shelke , The role of 2D material families in energy harvesting: An editorial overview, Journal of Materials Research., 37, 3857 - 3864 (2022).
Popat Jori & Vrushali Jadhav*, Highly Efficient Zirconium Based Carbonaceous Solid Acid Catalyst
for Selective Synthesis of 5?HMF from Fructose and Glucose
in Isopropanol as a Solvent, Catalysis Letters., 152, 1703 - 1710 (2022).
Swapnali P. Kirdant, Asma T. Biradar Tamboli And Vrushali H. Jadhav*, Recent Developments in the Applications of Biomass Derived Sulfonated Carbonaceous Solid Acid Catalysts, Helvetica Chem Acta., 105, e202200032 (2022).
Shubham R. Bankar, Swapnali P. Kirdant And Vrushali H. Jadhav*, Cobalt-immobilized carbon-based nano-catalyst for Csingle bondN cross coupling reaction, Results in Chemistry., 4, 100682 (2022).
Ganesh N. Kamble , Dheeraj Chandra Joshi And S.K. Asha, Design and synthesis of photocrosslinker and light blocker based on l-Amino acid polyester and their application in solvent-free resin formulation for DLP/SLA 3D printing, Polymer., 270, 125781 (2022), DOI:https://doi.org/10.1016/j.polymer.2023.125781.
Shibam Pal And Asha S. K, Biodegradable, Solvent-Free Photocrosslinkable PLLA Resin Formulations for Additive Manufacturing, macromolecular chemistry and physics., 223, 2200139 (2022), DOI:https://doi.org/10.1002/macp.202200139.
Navnath R. Kakde, H. J. Bharathkumar, Bhaiyyasaheb A. Wavhal, Arun Nikam, Suneha Patil, Soumya Ranjan Dash, Kumar Vanka, K. Krishnamoorthy, Amol Kulkarni And S. K. Asha, Direct (hetero)arylation (DHAP) polymerization
of conjugated polymers – new A–B–A monomer
design for P(NDI2OD-T2) & the challenges of
adopting DHAP for continuous flow processes, Journal of Materials Chemistry C., 10, 13025 (2022), DOI:DOI: 10.1039/d2tc02514k.
Shrikant B Nikam, Chandrodai Pratap Singh, Sailaja Krishnamurty And SK Asha, Structure-property insights into chiral thiophene copolymers by direct heteroarylation polymerization, European Polymer Journal., 181, 111676 (2022), DOI:https://doi.org/10.1016/j.eurpolymj.2022.111676.
Shrikant B. Nikam and Asha SK, Enantioselective Separation of Amino Acids Using Chiral Polystyrene Microspheres Synthesized by a Post-Polymer Modification Approach, ACS Polymers Au., 3, 257 - 265 (2022), DOI:https://doi.org/10.1021/acspolymersau.2c00004.
Vijayakrishnan Jeyavani and Shatabdi Porel Mukherjee*, Crystal Phase and Morphology-controlled Synthesis of Tungsten Oxide Nanostructures for Remarkably Ultrafast Adsorption and Separation of Organic Dyes, Inorganic Chemistry (full paper)., 61, 18119 - 18134 (2022), DOI:10.1021/acs.inorgchem.2c02715.
IF 5.436 (2021),
Simple inorganic routes for the synthesis of WO3 nanostructures with variable crystal phases, WO3·(H2O)0.5 and (NH4)0.33WO3, and their self-assembled structures as nanoplates and nanospheres, respectively, were reported. The morphologies and formation of nanoplates and nanospheres were controlled by changing the solvent amount (H2O/n-propanol) in the solvothermal reactions without any stabilizing agent or surfactant. The adsorption properties of the WO3 nanostructures were studied, and it was found that nanospheres show remarkably higher and ultrafast adsorption of methylene blue (MB) in comparison to nanoplates and commercial WO3. The adsorption isotherms, kinetics, mechanism, and reusability of (NH4)0.33WO3 nanospheres were systematically studied. The nanospheres exhibited an exceptionally high adsorption rate K2 of 17.24 g·mg–1·min–1 and the maximum adsorption capacity of 116 mg·g–1 for MB. The adsorption cycle of nanospheres was examined, and the removal efficiency of MB remained at ?98–99% even after three regeneration cycles. In addition, (NH4)0.33WO3 nanospheres exhibited excellent selective adsorption performance toward several cationic dyes, including MB, malachite green (MG), safranin O (SO), crystal violet (CV), and separate MO, a negatively charged dye, with a separation efficiency of 99.93 and 77.31% from binary and pentanary dye mixture solutions, respectively, at neutral pH.
Supriya Hanmant Gaikwad and Shatabdi Porel Mukherjee*, Synthesis of 2D MoO3-x/N-doped-Carbon Nanocomposite via in situ Carbonization of Layered (NH4)Mo3O9-(NH4)2Mo4O13-Organic Hybrid Nanomaterials for Exceptionally Efficient Adsorption and Separation of Organic Dye, Environmental Science: Nano, Advance Article., 9, 4508 - 4523 (2022), DOI:https://doi.org/10.1039/D2EN00668E.
MoO3-x/N-doped-carbon (MoO3-x/N-C) nanocomposites with nanobelt structures were prepared by the
in situ carbonization of the (NH4)Mo3O9–(NH4)2Mo4O13/oleylamine–oleic acid hybrids, and were designed
using a two-step tailored nanoemulsion method followed by a solvothermal process. The MoO3?x/N-C
nanocomposites possess high stability in a wide pH range of 1–11. In addition to the formation
mechanism, detailed studies on adsorption properties, including adsorption isotherms, kinetics, mechanism,
and reusability of the MoO3-x/N-C nanocomposites were systematically studied. The effects of various
parameters on the adsorption characteristics, such as adsorbate concentration, contact time, pH, and
temperature, were also evaluated. The detailed investigation of the kinetics and adsorption mechanism of
MB from an aqueous solution showed that the adsorption process follows a pseudo-second-order kinetics
and intraparticle diffusion model. The adsorption isotherm study demonstrated that the Langmuir isotherm
model could illustrate the experimental data with a maximum adsorption capacity value of ?1360 mg g-1,
which turns out to be the highest among the previously reported adsorbents based on MoO3
nanomaterials, and is attributed to multiple adsorption mechanisms including electrostatic, pi-pi stacking,
and H-bonding interactions between the MB dye and the MoO3-x/N-C nanocomposites. Thermodynamic
analysis suggested that MB adsorption onto the MoO3-x/N-C nanocomposites was spontaneous and
endothermic. Additionally, the adsorption and desorption cycles were examined for 100 ppm aqueous MB
solution, where the removal efficiency by the MoO3-x/N-C nanocomposites remained at ~99% even after
four regeneration cycles. Furthermore, the MoO3-x/N-C nanocomposites could selectively adsorb MB from
a binary solution mixture containing two times higher concentrations of an anionic dye, methyl orange
(MO), and the separation efficiency obtained was ~99% at neutral pH. More significantly, the MoO3-x/N-C
nanocomposites could successfully and simultaneously adsorb several cationic dyes, including MB,malachite green (MG), crystal violet (CV), safranin O (SO), and separate an anionic dye, MO, from quaternary
and pentanary dye mixture solutions with a separation efficiency of ~75% and 62%, respectively, at neutral
pH. To the best of our knowledge, the effective separation of a single component by molybdenum oxide-based
nanomaterials via a simple batch separation technique from a four/five-component mixed interfering
analyte, close to a real matrix system, in an aqueous medium at neutral pH has not been reported so far.
Therefore, the MoO3-x-based nanocomposite could be a new promising material for application in dye
K. Asokan, † M. K. Patil, † S. P. Mukherjee, * S. B. Sukumaran And * T. Nandakumar. (†Authors contributed equally), Scalable Mechanochemical Synthesis of Beta-Ketoenamine-linked Covalent Organic Frameworks for Methane Storage, Chemistry - An Asian Journal, VIP., 17, e202201012 - e202201012 (2022), DOI:https://doi.org/10.1002/asia.202201012.
IF : 4.568;
In the current scenario of increased pollution and releasing toxic gases by burning petroleum products, switching to natural gas is more promising for reducing CO2 emissions and air pollutants. Hence, research on Liquefied Natural Gas and Compressed Natural Gas is gaining more value. However, natural gas primarily consists of CH4, which has less energy density than conventional fuels. Interestingly, since the C?H ratio of CH4 gas is 1?:?4, it is easily combustible, gives less carbon footprint, and reduces unburnt hydrocarbon pollution. Hence, research on storing and transporting CH4 has utmost importance, and porous materials are one of the suitable candidates for storing CH4. Herein we report the scalable synthesis of highly porous and crystalline covalent organic frameworks for storing CH4 at room temperature and pressure. Two COFs, namely, Tp-Azo and Tp-Azo-BD(Me)2, synthesized in 1?kg at ?45?g batch scale using a Planetary mixer, displayed a maximum BET surface area of around 3345?m2/g, and 2342?m2/g and CH4 storage of 174.10?cc/cc and 151?cc/cc, respectively. A comparison of the CH4 sorption of Tp-Azo and Tp-Azo-BD(Me)2 COFs synthesized in different batches has a variation of only ±5?cc/cc and shows the consistency in bulk scale synthesis of COFs. The cyclic equilibrium CH4 adsorption studies showed the COFs are stable with consistent CH4 adsorption and desorption cycles. The present study is a step towards the scalable mechanochemical synthesis of COFs for gas storage applications.
Hariharakrishnan Chidambaram And Rashmi Das and Subashchandrabose Chinnathambi*, G-Protein coupled Purinergic P2Y12 receptor interacts and internalizes TauRD-mediated by membrane-associated actin cytoskeleton remodelling in microglia, European Journal of Cell Biology., , (2022).
Singh A K, Kavungathodi M F M, Mozer A J, Krishnamoorthy K And Nithyanandhan J, Solvent Dependent Functional Aggregates of Unsymmetrical Squaraine Dyes on TiO2 Surface for Dye-Sensitized Solar Cells, Langmuir., 38, 14808 - 14818 (2022), DOI:10.1021/acs.langmuir.2c02469.
Ashvini Deshmukh, M Thripuranthaka, Vikash Chaturvedi, Anoushka K Das, Vilas Shelke And Manjusha V Shelke*, A review on recent advancements in solid state lithium–sulfur batteries: fundamentals, challenges, and perspectives, Progress in Energy., 4, 042001 (2022).
Tapas Haldar, Srijan Chatterjee, Md Nirshad Alam, Pradip Maity And Sayan Bagchi, Blue Fluorescence of Cyano-tryptophan Predicts Local Electrostatics and Hydrogen Bonding in Biomolecules, J. Phys. Chem. B., 126, 10732 - 10740 (2022), DOI:https://doi.org/10.1021/acs.jpcb.2c05848.
V. Tammara And A Das, Governing dynamics and preferential binding of the AXH domain influence the aggregation pathway of Ataxin?1, Proteins: Struct. Funct. Bioinf., 1, 1 - 15 (2022), DOI:https://doi.org/10.1002/prot.26436.
Jadhav A P, Singh A K, Maibam A, Krishnamurty S, Krishnamoorthy K And Nithyanandhan J, D-A-D Based Unsymmetrical Thiosquaraine Dye for the Dye-Sensitized Solar Cells, Photochem. Photobiol., manuscript accepted, (2022).
Acharya N And Jha SK, Dry molten globule-like intermediates in protein folding, function and disease, J. Phys. Chem. B., 126, 8614 - 8622 (2022).
Devidas A. More, M. Mujahid, M And Muthukrishnan*, Metal- And Light-Free Direct C-3 Ketoalkylation of Quinoxalin-2(1H)-Ones with Cyclopropanols in Aqueous Medium, ChemistrySelect., 7, e202203597 (2022), DOI:https://doi.org/10.1002/slct.202203597.
Sachin R. Shirsath, Devidas A. More And M. Muthukrishnan*, Metal-Free Aminocarbonylation of p-Quinone Methides with Isocyanides: Synthesis of Sterically Hindered ?-Arylated Acetamides, Chemistry—An Asian Journal., 17, e202200642 (2022), DOI:https://doi.org/10.1002/asia.202200642.
Dinesh Patil, M.B.Sridhara, J.Manjanna, G.P.Nayaka And S.Sabale, Synthesis of ?-Fe2O3 nanoparticles from soft magnetic FeSiAl alloy cores of spent printed circuit boards and their application in visible-light-driven degradation of methylene blue dye, Ceramics International., 48, 35848 - 35859 (2022), DOI:https://doi.org/10.1016/j.ceramint.2022.08.103. [I. F. 5.5].
Mule, R. D.; Kumar, A.; Sancheti, S. P.; Senthilkumar, B.; Kumar, H.; Patil And N. T, BQ-AurIPr: a redox-active anticancer Au(I) complex
that induces immunogenic cell death, Chem. Sci., 13, 10779 - 10785 (2022), DOI:DOI: 10.1039/d2sc03756d.
Mali, N.; Senthilkumar And B, Synthesis of Novel Biological Active 1,2,4,-Triazole Analogues, Chem. Proc., 4, 1 - 4 (2022), DOI:https://doi.org/10.3390/xxxxx.
Srijan Chatterjee, Samadhan Deshmukh And Sayan Bagchi, Does Viscosity Drive the Dynamics in an Alcohol-Based Deep Eutectic Solvent?, J. Phys. Chem. B., 126, 8331 - 8337 (2022), DOI:https://doi.org/10.1021/acs.jpcb.2c06521.
Avdhoot Datar, Harshad Paithankar, Pranab Deb, Jeetender Chugh, Sayan Bagchi, Arnab Mukherjee And Anirban Hazra, Water-Controlled Keto–Enol Tautomerization of a Prebiotic Nucleobase, J. Phys. Chem. B., 126, 5735 - 5743 (2022), DOI:https://doi.org/10.1021/acs.jpcb.2c02507.
Suranjana Chakrabarty, Samadhan Deshmukh, Anajn Barman, Sayan Bagchi And Anup Ghosh, On–Off Infrared Absorption of the SO Vibrational Probe of Dimethyl Sulfoxide, J. Phys. Chem. B., 126, 4501 - 4508 (2022), DOI:https://doi.org/10.1021/acs.jpcb.1c10558.
Siddharth Ghule, Soumya Ranjan Dash, Sayan Bagchi, Kavita Joshi And Kumar Vanka, Predicting the Redox Potentials of Phenazine Derivatives Using DFT-Assisted Machine Learning, ACS Omega., 7, 11742 - 11755 (2022), DOI:https://doi.org/10.1021/acsomega.1c06856.
A. B. Shabade, D. M. Sharma, P. Bajpai, R. G. Gonnade, K. Vanka And B. Punji, Room Temperature Chemoselective Hydrogenation of C=C, C=O and C=N Bonds by Using a Well-Defined Mixed Donor Mn(I) Pincer Catalyst, Chem. Sci., 13, 13764 - 13773 (2022), DOI:10.1039/D2SC05274A.
Thangavel Vijayakanth, Supriya Sahoo, Premkumar Kothavade, Vijay Bhan Sharma, Dinesh Kabra, Jan K. Zar?ba*, Kadhiravan Shanmuganathan* And Ramamoorthy Boomishankar*, A Ferroelectric Aminophosphonium Cyanoferrate with a Large Electrostrictive Coefficient as Piezoelectric Nanogenerator, Angewandte Chemie Int. Ed., , (2022), DOI:https://doi.org/10.1002/ange.202214984.
Sachin Jadhav, Vivek Ganvir And Madan Singh* and Kadhiravan Shanmuganathan*, Synthesis of N-oxyethylene substituted imidazolium-based zwitterions as a recyclable solvent for cellulose dissolution, Cellulose., , (2022), DOI:https://doi.org/10.1007/s10570-022-04883-1.
Sutanu Nandi, Gauri Panditrao, Piyali Ganguli And Ram Rup Sarkar, PRESGENE: A web server for PRediction of ESsential GENE using integrative machine learning strategies, BioRxiv., , (2022), DOI:https://doi.org/10.1101/2022.11.25.517801.
P.R. Suresha and M.V. Badiger, Cationic chitosan graft flocculants: Synthesis, characterization and applications in kaolin separation, Materials Today: Proceedings., , (2022), DOI:https://doi.org/10.1016/j.matpr.2022.09.223.
Ajay Kumar, Kalaivani Chellappan, Aulia Nasution, Dnyandeo Pawar, Manoj Kumar Patel And Rajesh Kanawade, Diffuse reflectance-based spectroscopic technique for real-time estimation of localized blood oxygenation parameters from human fingertips: a preliminary study, Sensors & Diagnostics., 1, 1236 - 1242 (2022), DOI:https://doi.org/10.1039/D2SD00126H.
H Bhagavatula, A Sarkar, B Santra And A Das, Scan-Find-Scan-Model: Discrete Site-Targeted Suppressor Design Strategy for Amyloid-?, ACS Chemical Neuroscience., 13, 2191 - 2208 (2022), DOI:https://doi.org/10.1021/acschemneuro.2c00272.
B. P. Shivamurthy, M. Thripuranthaka, Manjusha V. Shelke And and G P Nayaka*, Formation of the Secondary Phase Domain by Multi-Cation Substitution for the Superior Electrochemical Performance of Spinel Cathodes for High-Voltage Li-Ion Batteries, ACS Applied Energy Materials., , (2022), DOI:https://doi.org/10.1021/acsaem.2c02667. [I. F. 6.9].
Samadhan S Nagane, Sachin S Kuhire, Amol B Ichake, Aniket A Talanikar, Bimlesh Lochab And Prakash P Wadgaonkar, Synthesis, Characterization and UV?Crosslinking of Aromatic (Co) polycarbonates Bearing Pendant Azido Groups, ChemistrySelect., 7, e202201020 (2022), DOI:10.1002/slct.202201020.
Uday A Jadhav, Samadhan S Nagane And Prakash P Wadgaonkar, Synthesis, characterization and post-modification of aromatic (Co) polyesters possessing pendant maleimide groups, High Performance Polymers., , 1 - 12 (2022), DOI:10.1177/09540083221127.
Samadhan S Nagane, Deepak M Maher, Savita Verma, Aniket A Talanikar And Prakash P Wadgaonkar, Pendant propargyloxy-functionalized aromatic (co) polycarbonates: synthesis, thermal crosslinking and chemical modification, Journal of Macromolecular Science, Part A., 59, 1 - 12 (2022), DOI:10.1080/10601325.2022.2117055.
Aniket A Talanikar, Samadhan S Nagane, Prakash P Wadgaonkar And Gajanan S Rashinkar, Post-polymerization modifiable aromatic (co) poly (ether sulfone) s possessing pendant norbornenyl groups based upon a new bisphenol, European Polymer Journal., 176, 111431 (2022), DOI:10.1016/j.eurpolymj.2022.111431.
Amol B Ichake, Samadhan S Nagane, Uday A Jadhav, Arun Torris, Etienne Grau, Henri Cramail And Prakash P Wadgaonkar, Synthesis and Characterization of Partially Biobased Aromatic (Co) polycarbonates Containing Biphenylene Units and Pendant Pentadecyl Chains, Macromolecular Chemistry and Physics., 223, 2100449 (2022), DOI:10.1002/macp.202100449.
Ketan Makwana, Amol B Ichake, Vinayak Valodkar, G Padmanaban, Manohar V Badiger And Prakash P Wadgaonkar, Cardol: Cashew nut shell liquid (CNSL)-derived starting material for the preparation of partially bio-based epoxy resins, European Polymer Journal., 166, 111029 (2022), DOI:10.1016/j.eurpolymj.2022.111029.
D. M. Sharma, C. Gouda, R. G. Gonnade And B. Punji, Room Temperature Z-selective Hydrogenation of Alkynes by Hemilabile and Non-innocent (NNN)Co(II) Catalyst, Catal. Sci. Technol., 12, 1843 - 1849 (2022), DOI:10.1039/D2CY00027J.
R. A. Jagtap, C. Pradhan, R. G. Gonnade And B. Punji, An Efficient Route to 3,3'-Biindolinylidene-diones by Iron-Catalyzed Dimerization of Isatins, Chem. Asian J., 17, xxxx - xxxx (2022), DOI:10.1002/asia.202200414.
S. K. Verma And B. Punji, Manganese-Catalyzed C(sp2)-H Alkylation of Indolines and Arenes
with Unactivated Alkyl Bromides, Chem. Asian J., 17, e202200103 (2022), DOI:10.1002/asia.202200103.
S. Sudhakaran, P. G. Shinde, E. K. Aratikatla, S. H. Kaulage, P. Rana, R. S. Parit, D. S. Kavale, B. Senthilkumar And B. Punji, Nickel-Catalyzed Asymmetric Hydrogenation for the Synthesis of Key Sitagliptin Intermediate, Chem. Asian J., 17, e202101208 (2022), DOI:10.1002/asia.202101208.
Rupa Bhowmick And Ram Rup Sarkar, Identification of potential microRNAs regulating metabolic plasticity and cellular phenotypes in glioblastoma, Molecular Genetics and Genomics., , (2022), DOI:https://doi.org/10.1007/s00438-022-01966-3.
Sanjukta Pahar, Vishal Sharma, Biplab mahata, Christy P. George, Himanshu Sharma, Kumar Vanka And Sakya S. Sen*, Tridentate NacNac Stabilized Tin and Nickel Complexes: Access to a Monomeric Nickel Hydride and Its Catalytic Application, Inorg. Chem., 61, 17370 - 17377 (2022).
Maria Kurian, Meena Ghosh, Vidyanand Vijayakumar, P P Priyanka, Arun Torris And Sreekumar Kurungot, Influence of Ice-templating on Oxygen Redution Catalytica Activity of Metal-free Heteroatom-doped Mesoporous Carbon Derived from Polypyrrole for Zinc-air Batteries, Energy Technology., 2200840, (2022), DOI:10.1002/ente.202200840.
Narugopal Manna, Santosh Singh, Maria Kurian, Arun Torris And Sreekumar Kurungot, Air-Cathode Interface-Engineered Electrocatalyst for Solid-State Rechargeable Zinc-Air Batteries, ACS Applied Energy Materials., 5 (7), 8756 - 8768 (2022), DOI:10.1021/acsaem.2c01266.
Sahel Fajal, Writakshi Mandal, Samraj Mollick, Yogeshwar More, Arun Torris, Satyam Saurabh, Mandar Shirolkar And Sujit Ghosh, Trap Inlaid Cationic Hybrid Composite Material for Efficient Segregation of Toxic Chemicals from Water, Angewandte Chemie., 61 (32), e202203385 (2022), DOI:10.1002/anie.202203385.
Sagar Dadasaheb, Srinath Gudur, Vishwanath Nagallapati, Amit Choudhary, Arun Torris And Gopinath Muvvala, A Study on Anisotropy in Wire Arc Additively Manufactured Inconel 625 Multi-layered Wall and its Correlation with Molten Pool Thermal History, Material Science and Engineering: A., 840, 142865 (2022), DOI:10.1016/j.msea.2022.142685.
Amol Ichake, Samadhan Nagane, Uday Jadhav, Arun Torris, Etienne Grau, Henri Cramail And Prakash Wadgaonkar, Synthesis and Characterization of Partially Bio-Based Aromatic (Co)polycarbonates Containing Biphenylene Units and Pendant Pentadecyl Chains, Macromolecular Chemistry and Physics., 223 (13), 2100449 (2022), DOI:10.1002/macp.202100449.
Thripuranthaka M, Vikash Chaturvedi, Pravin Dwivedi, Arun Torris And Manjusha Shelke, 3D X-ray Microtomography Investigations on the Bimodal Porosity and High Sulfur Impregnation in 3D Carbon Foam for Li-S Battery Application, Journal of Physics Energy., 4 (1), 014003 (2022), DOI:10.1088/2515-7655/ac4c34.
Kanungo, Subhashree; Mishra, Abhaya; Mhamane, Nitin; Marelli, Uday Kiran; Kumar And Dharmesh; and Gopinath Chinnakonda, Possible Fine-tuning of Methane Activation Towards C2 Oxygenates by 3d Transition Metal-ions Doped Nano Ceria-Zirconia, ACS Inorganic Chemistry., , (2022), DOI:Just accepted.
Ravi Ranjan, Nitin B. Mhamane, Sadhu K. Kolekar And and Chinnakonda S. Gopinath*, Electronic Structure Evolution from Metallic Vanadium to Metallic VxOy: A NAPPES Study for O2 + V Gas–Solid Interaction, The Journal of Physical Chemistry C., , (2022), DOI:https://doi.org/10.1021/acs.jpcc.2c05212.
Anjani Dubey, Abhaya Kumar Mishra, Sanjay Singh Negi And Chinnakonda S Gopinath, Facile, sustainable and unassisted plain water oxidation on Au/Ce0.9Ti0.1O2 nanorods in direct sunlight, Journal of Chemical Science., 134, 61 (2022), DOI:10.1007/s12039-022-02055-z.
Chinnakonda Subramanian Gopinath And Raja Ambal Sivaraman, Photostable composite for solar water splitting and process for the preparation thereof, US Patent., , (2022), DOI:US11325113B2.
Luma Mirely de Souza Brandão, Milson dos Santos Barbosa, Roberta Anjos de Jesus, Pradnya Arunrao Bharad, Álvaro Silva Lima, Cleide Mara Faria Soares, Rufino Manuel Navarro Yerga, Muhammad Bilal, Luiz Fernando Romanholo Ferreira, Hafiz MN Iqbal, Chinnakonda S Gopinath And Renan Tavares Figueiredo, Enhanced hydrogen fuel production using synergistic combination of solar radiation and TiO2 photocatalyst coupled with Burkholderia cepacia lipase, International Journal of Hydrogen Energy., , (2022), DOI:10.1016/j.ijhydene.2022.02.220.
Naeemakhtar Momin, J. Manjanna, Satoru Kobayashi, T. Aruna And Senthil Kumarc and G. P. Nayaka, Synthesis and ionic conductivity of calcium-doped
ceria relevant to solid oxide fuel cell applications, Materials Advances., , (2022), DOI:DOI: 10.1039/d2ma00868h.
Rohit Kumar, Sanjukta Pahar, Joy Chatterjee, Soumya Ranjan Dash, Rajesh G. Gonnade, Kumar Vanka And Sakya S. Sen*, Luminescent magnesium complexes with intra- and inter-ligand charge transfer, Chem. Commun., 58, 11843 - 11846 (2022).
Rohit Kumar, Sayan Dutta, Vishal Sharma, Praval P. Singh, Rajesh G. Gonnade*, Debasis Koley* And Sakya S. Sen*, Monomeric Magnesium Catalyzed Alkene and Alkyne Hydroboration, Chem. Eur. J., 28, e202201896 - (1-8) (2022).
Highlighted in Chemistry views: https://www.chemistryviews.org/monomeric-magnesium-complexes-for-catalysis/
Selected for Inside Front Cover.
The first two authors contributed equally
Gargi Kundu, Ruchi Dixit, Srinu Tothadi, Kumar Vanka And Sakya S. Sen*, Versatile chemistry of six-membered NHC with boranes: bromination at sp3 borane, activation of the B–H bond of HBpin, and ring expansion of NHC, Dalton Trans., 51, 14452 - 14457 (2022).
Selected for Inside Front Cover
N V Dambhare, A Sharma, C Mahajan And Arup K Rath*, Thiocyanate and Thiol Functionalized p-Doped Quantum Dot Colloids for the Development of Bulk Homojunction Solar Cells, Energy Technol., 10, 2200455 (2022).
J Bera, A Betal, A Sharma, Arup K. Rath And S Sahu, Colloidal MoS2 quantum dots for high-performance low power resistive memory devices with excellent temperature stability, Appl. Phys. Lett., 120, 253502 (2022).
J Bera, A Betal, A Sharma, U Shankar, Arup K. Rath And S Sahu, CdSe Quantum Dot-Based Nanocomposites for Ultralow-Power Memristors, ACS Appl. Nano Mater., 5, 8502 - 8510 (2022).
A Betal, J Bera, A Sharma, Arup K. Rath And S Sahu, Composition and Surface Morphology Invariant High On–Off Ratio from an Organic Memristor, ACS Appl. Electron. Mater., 5, 1109 - 1116 (2022).
Doke AA And Jha SK, Effect of in-vitro solvation condition on inter and intra-molecular assembly of full-length TDP-43, J. Phys. Chem. B., 126, 4799 - 4813 (2022).
Pawan Kumar, Anuradha Vijay Jagtap, Sharad Gupta And C. P. Vinod*, La Cu based heterogeneous perovskite catalyst for highly selective
benzene hydroxylation under mild conditions, Chem Asian J., , (2022), DOI:10.1002/asia.202200788.
C P Vinod And Vysakh Alengattil Bharathan, Process for the preparation of bimetallic core/shell nanoparticles and their catalytic applications, US Patent 11,305,344 B2., , (2022).
S Mondal, D Bagchi, M Riyaz, S Sarkar, AK Singh, CP Vinod And SC Peter, In Situ Mechanistic Insights for the Oxygen Reduction Reaction in Chemically Modulated Ordered Intermetallic Catalyst Promoting Complete Electron Transfer, Journal of the American Chemical Society., 144, 26, 11859 - 11869 (2022), DOI:10.1021/jacs.2c04541.
Risov Das, Kousik Das, Bitan Ray, C P Vinod And Sebastian C Peter*, Green Transformation of CO2 to Ethanol using Water and Sunlight by Cooperative Endeavour of Naturally Abundant Red Phosphorus and Bi2MoO6, Energy and Environmental Science., , (2022), DOI:doi.org/10.1039/D1EE02976B.
D Goud, SR Churipard, D Bagchi, AK Singh, M Riyaz, CP Vinod And SC Peter*, Strain-Enhanced Phase Transformation of Iron Oxide for Higher Alcohol Production from CO2, ACS Catalysis., 12 (18), 11118 - 11128 (2022), DOI:10.1021/acscatal.2c03183.
Soumi Mondal, Shreya Sarkar, Debabrata Bagchi, Tisita Das, Risov Das, Ashutosh Kumar Singh, Ponnappa Kechanda Prasanna, CP Vinod, Sudip Chakraborty And Sebastian C Peter*, Morphology Tuned Pt3Ge Accelerates Water Dissociation to Industrial Standard Hydrogen Production over a wide pH Range, Advanced Materials., 34, 2202294 (2022), DOI:10.1002/adma.202202294.
Debabrata Bagchi, Jithu Raj, Ashutosh Kumar Singh, Arjun Cherevotan, Soumyabrata Roy, Kaja Sai Manoj, CP Vinod And Sebastian C. Peter*, Structure-Tailored Surface Oxide on Cu-Ga Intermetallics Enhances CO2 Reduction Selectivity to Methanol at Ultra-Low Potential, Advanced Materials., 34 (19), 2109426 (2022), DOI:doi.org/10.1002/adma.202109426.
Lipipuspa Sahoo, Reeya Garg, Komalpreet Kaur, C. P. Vinod And Ujjal K. Gautam*, Ultrathin Twisty PdNi Alloy Nanowires as Highly Active ORR Electrocatalysts Exhibiting Morphology-Induced Durability over 200 K Cycles, Nano Letters., , (2022), DOI:10.1021/acs.nanolett.1c03704.
Risov Das, Shreya Sarkar, Ritesh Kumar, Seethiraju D. Ramarao, Arjun Cherevotan, Mohammed Jasil, C. P. Vinod, Abhishek Kumar Singh And Sebastian C. Peter*, Noble-Metal-Free Heterojunction Photocatalyst for Selective CO2 Reduction to Methane upon Induced Strain Relaxation, ACS Catalysis., , 687 - 697 (2022), DOI:10.1021/acscatal.1c04587.
Arjun Cherevotan, Bitan Ray, Sathyapal R Churipard, Komalpreet Kaur, Ujjal K Gautam, C P Vinod And Sebastian C Peter*, Influence of Support Textural Property on CO2 to Methane Activity of Ni/SiO2 Catalysts, Applied Catalysis B: Environmental., 317, 121692 (2022), DOI:10.1016/j.apcatb.2022.121692.
Chandana Chandran, Himan Dev Singh, Liya S Leo, Pragalbh Shekhar, Deepak Rase, Debanjan Chakraborty, C. P. Vinod And Ramanathan Vaidhyanathan*, A covalent organic framework with electrodeposited copper nanoparticles–a desirable catalyst for the Ullmann coupling reaction, Journal of Materials Chemistry A., 10(29), 15647 - 15656 (2022), DOI:10.1039/D2TA01326F.
Arjun Cherevotan, Bitan Ray, Anish Yadav, Debabrata Bagchi, Ashutosh Kumar Singh, Mohd Riyaz, Sathyapal R Churipard, Vinay Naral, Komalpreet Kaur, Ujjal K Gautam, C. P. Vinod And Sebastian C Peter*, Tuning the hybridization and charge polarization in metal nanoparticles dispersed over Schiff base functionalized SBA-15 enhances CO 2 capture and conversion to formic acid, Journal of Materials Chemistry A., 10(35), 18354 - 18362 (2022), DOI:10.1039/D2TA03690H.
Soumya K, I. Packia Selvam, C P Vinod And S. N. Potty*, Tuning of work function of ZnO by doping and co-doping: An investigation using X-ray photoelectron spectroscopy, Thin Solid Films., , (2022), DOI:(just accepted).
S Vashishth, DK Singh, C. P. Vinod And E Muthusamy*, Single step strategy for crafting tin/carbon soot composite as highly stable Li?ion battery anode, Electrochemical Science Advances., , (2022), DOI:10.1002/elsa.202100019.
Sanchayita Mukhopadhyay, Mruthyunjayachari Chattanahalli Devendrachari, Sandeep C Kanade, C. P. Vinod, Harish Makri Nimbegondi Kotresh And Musthafa Ottakam Thotiyl*, Regio-isomerism Directed Electrocatalysis for Energy Efficient Zinc-air Battery, iScience., , (2022), DOI:10.1016/j.isci.2022.105179.
Sattwick Haldar, Deepak Rase, Pragalbh Shekhar, Chitvan Jain, C. P. Vinod, En Zhang, Leonid Shupletsov, Stefan Kaskel And Ramanathan Vaidhyanathan, Incorporating Conducting Polypyrrole into a Polyimide COF for Carbon?Free Ultra?High Energy Supercapacitor, Advanced Energy Materials., 12 (34), 2200754 (2022), DOI:10.1002/aenm.202200754.
P R Suresha And Manohar V Badiger, Cationic chitosan graft flocculants: Synthesis, characterization and applications in kaolin separation, Materials Today: Proceedings., , (2022), DOI:10.1016/j.matpr.2022.09.223.
Article in press
Singh A K, Sudhkar V, Bisht R, Javaregowda B H, Krishnamoorthy K And Nithyanandhan J, Modular TiO2-Squaraine Dyes/Electrolyte Interface for the Dye-Sensitized Solar Cells with Cobalt Electrolyte, ChemPhotoChem., manuscript accepted, (2022), DOI:10.1002/cptc.202200171.
Geeta Pandurang Kharabe, Narugopal Manna, Ayasha Nadeema, Santosh K Singh, Shweta Mehta, Aathira Nair, Kavita Joshi And Sreekumar Kurungot, A pseudo-boehmite AlOOH supported NGr composite-based air electrode for mechanically rechargeable Zn-air battery applications, Journal of Materials Chemistry A., 10, 10014 - 10025 (2022), DOI:https://doi.org/10.1039/D2TA00546H.
Both mechanically and electrically rechargeable zinc-air batteries (ZABs) have received much interest due to their high energy density and suitability for mobile and stationary applications. However, their commercialization has been impeded by the lack of robust, low-cost and environmentally benign catalyst materials that can be easily scaled up. In this context, the present work introduces a new type of transition metal-free catalytic material (AlOOH/NGr) by anchoring the pseudo-boehmite phase of aluminium oxyhydroxide (AlOOH) nanosheets over nitrogen-doped graphene (NGr) via a single-step and straightforward hydrothermal process. Furthermore, density functional theory (DFT) based computation demonstrates that the nucleation of AlOOH starts from the N-sites and points towards the strong surface interaction between AlOOH and NGr via doped nitrogen. AlOOH/NGr consisting of thin layered pseudo-boehmite sheets uniformly distributed over NGr has displayed an oxygen reduction reaction onset potential of 0.83 V and a half-wave potential of 0.72 V, along with good catalytic durability in alkaline medium. With this, AlOOH/NGr, when used as an air electrode for fabricating a primary Zn-air battery, the system has exhibited an open circuit voltage of ?1.27 V with a flat discharge profile at a current rate of 10 mA cm?2. The fabricated system delivered a specific capacity of ?720 mA h g?1 and a high power density of 204 mW cm?2 and is comparable to the counterpart system based on the state-of-the-art Pt/C (20 wt% Pt) cathode. Additionally, the homemade battery was able to maintain its performance after 4 times of mechanical recharging of the battery, which lasted for more than 35 h at a discharge current density of 10 mA cm?2. Thus, we have uncovered the potential of an earth-abundant metal-based catalytic system for fabricating and demonstrating a robust mechanically rechargeable zinc-air battery.
Siddharth Ghule, Soumya Ranjan Dash, Sayan Bagchi, Kavita Joshi And Kumar Vanka, Predicting the Redox Potentials of Phenazine Derivatives Using DFT-Assisted Machine Learning, ACS omega., 7, 11742 - 11755 (2022), DOI:https://doi.org/10.1021/acsomega.1c06856.
This study investigates four machine-learning (ML) models to predict the redox potentials of phenazine derivatives in dimethoxyethane using density functional theory (DFT). A small data set of 151 phenazine derivatives having only one type of functional group per molecule (20 unique groups) was used for the training. Prediction accuracy was improved by a combined strategy of feature selection and hyperparameter optimization, using the external validation set. Models were evaluated on the external test set containing new functional groups and diverse molecular structures. High prediction accuracies of R2 > 0.74 were obtained on the external test set. Despite being trained on the molecules with a single type of functional group, models were able to predict the redox potentials of derivatives containing multiple and different types of functional groups with good accuracies (R2 > 0.7). This type of performance for predicting redox potential from such a small and simple data set of phenazine derivatives has never been reported before. Redox flow batteries (RFBs) are emerging as promising candidates for energy storage systems. However, new green and efficient materials are required for their widespread usage. We believe that the hybrid DFT-ML approach demonstrated in this report would help in accelerating the virtual screening of phenazine derivatives, thus saving computational and experimental costs. Using this approach, we have identified promising phenazine derivatives for green energy storage systems such as RFBs.
Kavita Joshi And Shweta Mehta, From molecular adsorption to decomposition of methanol on various ZnO facets: A periodic DFT study, Applied Surface Science., 602, 154150 (2022), DOI:https://doi.org/10.1016/j.apsusc.2022.154150.
Methanol is an interesting and important molecule to study because of its potential to replace existing fuels. It is also a prominent hydrogen source which can be used to generate hydrogen in-situ. ZnO is widely used as catalyst in synthesis of methanol from CO2 at industrial scale. In this work, we demonstrate that the same catalyst could be used for MeOH decomposition. We have investigated interaction of methanol with various flat and stepped facets of ZnO by employing Density Functional Theory (DFT). Two flat [(100) and (110)] and two stepped [(103) and (112)] facets are studied in detail for methanol adsorption. Chemisorption of MeOH with varying strength is common to all four facets. Most importantly spontaneous dissociation of O-H bond of methanol is observed on all facets except (110). Our DFT calculations reveal that molecular adsorption is favored on flat facets, while dissociation is favored on step facets. Also, (100) facet undergoes substantial reconstruction upon MeOH adsorption. Activation of C-H bond along with strengthening of C-O bond on ZnO facets suggest partial oxidation of methanol. With our DFT investigations, we dig deeper into the underlying electronic structure of various facets of ZnO and provide rationale for the observed facet dependent interaction of ZnO with MeOH.
Meema Bhati, Jignesh Dhumal And Kavita Joshi, Lowering the C-H Bond Activation Barrier of Methane Using SAC@Cu(111): A Periodic DFT Investigations, The New Journal of Chemistry., 46, 70 - 74 (2022), DOI:https://doi.org/10.1039/D1NJ04525C.
Methane has long captured the world's spotlight for being the simplest and yet one of the most notorious hydrocarbon. Exploring its potential to be converted into value added products has raised a compelling interest. In the present work, we have studied the efficiency of Single-Atom Catalysts (SACs) for methane activation employing Density Functional Theory (DFT). The Climbing Image-Nudged Elastic Bond (CI-NEB) method is used in tandem with the Improved Dimer (ID) method to determine the minimum energy pathway for the first C-H bond dissociation of methane. Our study reported that the transition-metal doped Cu(111) surfaces enhance adsorption, activate C-H bond, and reduce activation barrier for first C-H bond cleavage of methane. The results suggest Ru/Co/Rh doped Cu(111) as promising candidates for methane activation with minimal activation barrier and less endothermic reaction. For these SACs, the calculated activation barriers for first C-H bond cleavage are 0.17 eV, 0.24 eV, and 0.26 eV respectively, which is substantially lower than 1.13 eV, the activation barrier for Cu(111).
Aathira Nair, Nivedita Kenge And Kavita Joshi, Role of facet in the competitive pathway of ethylene epoxidation, Surface Science., 716, 121954 (2022), DOI:https://doi.org/10.1016/j.susc.2021.121954.
Ethylene epoxide (EtO) is used as raw material for a broad range of products from pharmaceuticals and plastics to paints and adhesives. Although the reaction of ethylene interacting with preadsorbed oxygen on Ag surface is known for decades, the underlying mechanism of EtO formation is not completely understood. Successful investigation of oxametallacycle (OMC) intermediate common to selective as well as non-selective path- ways has ensured at least 50% selectivity. The current study brings out the electronic signatures of distinct conformers of OMC stabilized on two different facets of Ag viz. (100) and (111). There are subtle differences between OMC conformers observed on these two facets with near-eclipsed on Ag(100) and near- staggered on Ag(111). A de- tailed analysis of Ag-O, C-O, C-C, and Ag-C interactions along with projected Density of States (pDOS) and projected Crystal Orbital Hamilton Population (pCOHP) imply towards ring closure on Ag(100) and hydrogen transfer on Ag(111). Finally, our un derstanding based on electronic and structural signatures are backed up by activation barriers computed through NEB calculations. Activation barrier for EtO is lower on ( 100) as compared to (111) facet. Thus, our study sheds light on how these differences between OMC affect the selectivity towards EtO.
Sheena Agarwal and Kavita Joshi, Looking Beyond Adsorption Energies to Understand Interactions at Surface Using Machine Learning, ChemistrySelect., , (2022), DOI:10.26434/chemrxiv.14726184.v1.
AbstractIdentifying factors that influence interactions at the surface is still an active area of research. In this study, we present the importance of analyzing bondlength activation, while interpreting Density Functional Theory (DFT) results, as yet another crucial indicator for catalytic activity. We studied theadsorption of small molecules, such as O 2 , N 2 , CO, and CO 2 , on seven face-centered cubic (fcc) transition metal surfaces (M = Ag, Au, Cu, Ir, Rh, Pt, and Pd) and their commonly studied facets (100, 110, and 111). Through our DFT investigations, we highlight the absence of linear correlation between adsorption energies (E ads ) and bondlength activation (BL act ). Our study indicates the importance of evaluating both to develop a better understanding of adsorption at surfaces. We also developed a Machine Learning (ML) model trained on simple periodic table properties to predict both, E ads and BL act . Our ML model gives an accuracy of Mean Absolute Error (MAE) ? 0.2 eV for E ads predictions and 0.02 Å for BL act predictions. The systematic study of the ML featuresthat affect E ads and BL act further reinforces the importance of looking beyond adsorption energies to get a full picture of surface interactions with DFT
G.Santhosh And G.P.Nayaka, Nano Clay Reinforcement of Thermoplastics for Engineering Applications, Materials Research Foundations., 129, 108 - 128 (2022), DOI:https://doi.org/10.21741/9781644902035-5, (Book chapter).
Vijayakrishnan Jeyavani, Rajendra Kumar, Pattayil Alias Joy And and Shatabdi Porel Mukherjee*, MgB2/NaNO2-PVA Free-standing Polymer Composite Film as a Green Firework: A Step towards Environmental Sustainability, Bulletin of Materials Science., 45, 175 (1-9) (2022), DOI:https://doi.org/10.1007/s12034-022-02756-8.
We have demonstrated a simple fabrication methodology of free-standing polymer composite film firework
that sparkles, provides colour display and moderate sound, yet is less polluting. The polymer composite film fireworks are
composed of magnesium boride (MgB2), sodium nitrite (NaNO2) and poly(vinyl alcohol) (PVA). This study also suggested
that a flammable, explosive powder composition can be made of two very common inorganic precursors, mainly
NaNO2 and MgB2. This is the first report demonstrating composite film fireworks with new flammable composition using
metal boride as a primary precursor, which can also be used in conventional fireworks fabrication, replacing the traditional
fuel, mainly gunpowder. The film fireworks were free from charcoal, sulphur, metal powder and paper. Therefore, they
substantially lower the odour and COx, NOx emissions and minimize the substantial trash generated when burned. Most
importantly, film firework‘s minimum ignition temperature and exothermic decomposition temperature are much higher
than the ambient temperature; hence are safe to handle.
IF: 1.983 (2021)
Priyanka Gawade, Sutanu Nandi, Chandrakala Meena And Ram Rup Sarkar*, Artificial Intelligence and Machine Learning Techniques using Omics Data for Cancer Diagnosis and Treatment, In: Singh S. (eds) Systems Biomedicine Approaches in Cancer Research, Springer, Singapore., Print ISBN 978-981-19-1952-7, 23 - 50 (2022), DOI:10.1007/978-981-19-1953-4.
Gargi Kundu, Kajal Balayan, Srinu Tothadi And Sakya S. Sen*, Six-membered Saturated NHC Stabilized Borenium Cations: Isolation of a Cationic Analogue of Borinic Acid, Inorg. Chem., 61, 12991 - 12997 (2022).
Indrapal Karbhal, Vikash Chaturvedi, Apurva Patrike, Poonam Yadav And Manjusha V. Shelke*, Honeycomb Boron Carbon Nitride as High-Performance Anode Material for Li-Ion Batteries, ChemNanoMat., 8, e202200056 (2022).
Apurva Patrike, Poonam Yadav, Vilas Shelke And Manjusha Shelke*, Research Progress and Perspective on Lithium/Sodium Metal Anode for Next-Generation Rechargeable Batteries: a Review, ChemSusChem., 15, e202200504 (2022).
Neha Tiwari, Manohar V Badiger, P R Rajamohanan And Sapna Ravindranathan, Investigation of domain structures in monomethoxy poly(ethylene glycol)-b-poly(caprolactone) grafted poly(acrylic acid) by NMR diffusion studies, Polymer International., 71, 976 - 984 (2022), DOI:10.1002/pi.6380.
Farsa Ram, Prashant Yadav And Kadhiravan Shanmuganathan, Nanocellulose/melanin-based composites for energy, environment, and biological applications, J. Mater. Sci., , (2022), DOI:https://doi.org/10.1007/s10853-022-07512-1.
Siddharth K. Deepake, Manish Kumar, Pawan Kumar And Utpal Das, alpha-Angelica Lactone Catalysed Oxidation of Pyrrolidines to Lactams, Eur. J. Org. Chem., , xxxx - xxxx (2022), DOI:10.1002/ejoc.202200712.
Gargi Kundu, Srinu Tothadi And Sakya S. Sen*, Nucleophilic Substitution at a Coordinatively Saturated Five-Membered NHC-Haloborane Centre, Inorganics., 10, 97 (1 - 13) (2022).
This article belongs to the Special Issue Fifth Element: The Current State of Boron Chemistry
Kritika Gour, Milan Kumar Bisai And Sakya S. Sen*, Hypersilyl Substituent in Heavier Low-valent Group 14 Chemistry, Eur. J. Inorg. Chem., e202200071, 1 - 14 (2022).
Rohit Kumar, Vishal Sharma, Shailja Jain, Himanshu Sharma, Kumar Vanka And Sakya S. Sen*, A Well-Defined Calcium Compound Catalyzes Trimerization of Arylisocyanates into 1,3,5-Triarylisocyanurates, ChemCatChem., 14, e202101788 - (1-6) (2022).
Part of a joint Special Collection on “Main Group Catalysis”
Sivasankar Kakku, Shripal M. Gaikwad, Shashank G. Gaikwad, Suyogkumar V. Taralkar, Sarath Babu Billa, Anand Gupta Chakinala And Nandana Chakinala, Reactive Extraction of Gluconic Acid Using Trioctylamine in Different Diluents, Chemical Engg. and Technology., 45, 417 - 424 (2022), DOI:https://doi.org/10.1002/ceat.202100373.
Soumita Chakraborty, Shivanna Marappa, Sakshi Agarwal, Debabrata Bagchi, Ankit Rao, Chathakudath P Vinod, Sebastian C Peter, Abhishek Singh And Muthusamy Eswaramoorthy, Improvement in Oxygen Evolution Performance of NiFe Layered Double Hydroxide Grown in the Presence of 1T-Rich MoS2, ACS Applied Materials & Interfaces., , (2022), DOI:10.1021/acsami.2c06210.
Reeya Garg, Lipipuspa Sahoo, Komalpreet Kaur, CP Vinod And Ujjal K Gautam, Single-step insertion of M-Nx moieties in commercial carbon for sustainable bifunctional electrocatalysis: Mapping insertion capacity, mass loss, and carbon reconstruction, Carbon., 196, 1001 - 1011 (2022), DOI:10.1016/j.carbon.2022.06.008.
2. Mule, R.D.; Roy, R.; Mandal, K.; Chopra, D.; Dutta, T.; Sancheti, P.S.; Shinde, S.P.; Banerjee, S.; Koner, A.L.; Bhowal, R.; Senthilkumar, B.; Patil And N.T. , Interplay of Anion ??+ and ?+ ??+ Interactions in Novel Pyrido[2,1- Fluorescence Modulation and Applications in Live Cell Mitochondrial Imaging, Chem. Eur. J., , e202200632 (2022).
Lakshmi Goswami‡, Lovely Gupta‡, Sayantan Paul, Maansi Vermani And Pooja Vijayaraghavan* and Asish K. Bhattacharya*, Design and synthesis of eugenol/isoeugenol glycoconjugates and other analogues as antifungal agents against Aspergillus fumigatus†, RSC Med. Chem., , (2022), DOI:DOI: 10.1039/D2MD00138A.
Lovely Gupta, Pooja Sen, Asish K. Bhattacharya And Pooja Vijayaraghavan, Isoeugenol affects expression pattern of conidial hydrophobin gene
RodA and transcriptional regulators MedA and SomA responsible
for adherence and biofilm formation in Aspergillus fumigatus, Archives of Microbiology (Springer)., 204:214, 1 - 14 (2022), DOI:https://doi.org/10.1007/s00203-022-02817-w.
Someshwar B. Kale, Popat K. Jori And Utpal Das*, Rongalite as a Sulfone Source: Sulfonylation of para -Quinone Methides and Alkyl/allyl Halides, Chemistry-An Asian Journal., xx, xxxx - xxxx (2022), DOI:10.1002/asia.202200408.
Lisni P Sunny, Priya Srikanth, Anju Kunhiraman Sunitha, Niyoti Tembulkar And Jancy Nixon Abraham* , Tryptophan-Cardanol fluorescent nanoparticles inhibit alpha-synuclein aggregation and disrupt amyloid fibrils, Journal of Peptide Science., , (2022).
Singh A K And Nithyanandhan J, Indoline-Based Donor-pi-Acceptor Visible-Light Responsive Organic Dyes for Dye-sensitized Solar Cells: Co-Sensitization with Squaraine Dye for Panchromatic IPCE Response, ACS Appl. Energy Mater., 5, 1858 - 1868 (2022), DOI:10.1021/acsaem.1c03343.
Asma T. Biradar Tamboli And Swapnali P. Kirdant and Vrushali H. Jadhav*, Metal-free approach towards efficient synthesis of FDCA using a p-toluene sulfonic acid (p-TSA)-derived heterogeneous solid acid catalyst and oxone over two steps from HMF, fructose and glucose, New Journal of Chemistry., 46, 10272 - 10279 (2022), DOI:DOI https://doi.org/10.1039/D2NJ01207C.
Kritika Gour And Sakya S. Sen*, Applications of Germylenes in Catalysis, Ed. Rebecca Melen, Encyclopedia of Inorganic and Bioinorganic Chemistry., , (2022), DOI:10.1002/9781119951438.eibc2832.
Invited Book Chapter
Hasna M. Abdul Hakkeem, Aswathy Babu, Nagaraju Shilpa, Adithya A.Venugopal, A.P.Mohamed, SreekumarKurungot And Saju Pillai, Tailored synthesis of ultra-stable Au@Pd nanoflowers with enhanced catalytic properties using cellulose nanocrystals, Carbohydrate Polymers., 295, 119723 (2022), DOI:10.1016/j.carbpol.2022.119723.
Garima Tiwari, C P Vinod And Balaji R Jagirdar*, Controlled exchange bias behavior of manganese nanoparticles, Journal of Magnetism and Magnetic Materials., , 169504 (2022), DOI:10.1016/j.jmmm.2022.169504.
D Bagchi, S Sarkar, AK Singh, CP Vinod And SC Peter*, Potential- and Time-Dependent Dynamic Nature of an Oxide-Derived PdIn Nanocatalyst during Electrochemical CO2 Reduction, ACS Nano., 16 (4), 6185 - 6196 (2022), DOI:10.1021/acsnano.1c11664.
Thripuranthaka M., Vikash Chaturvedi, Pravin Kumari Dwivedi, Arun Torris And Manjusha V Shelke*, 3D X-ray microtomography investigations on the bimodal porosity and high sulfur impregnation in 3D carbon foam for Li-S battery application, JPhys Energy., 4, 014003 (2022).
R. Mei, R. C. Samanta, U. Dhawa, W. Ma And L. Ackermann, Electrochemical Cobalt-Catalyzed C–H Activations with Potential, in The Chemistry of Organocobalt Chemistry (Eds.: C. Gosmini, I. Marek), Wiley-VCH, Weinheim., , (2022).
Pragnya Paramita Samal, Amuthan Dekshinamoorthy, Shivakami Arunachalam, Saranyan Vijayaraghavan And Sailaja Krishnamurty, Free Base Phthalocyanine Coating as A Superior Corrosion Inhibitor for Copper Surfaces: A Combined Experimental and Theoretical Study, Colloids and Surfaces A: Physicochemical and Engineering Aspects., 648, 129138 (2022), DOI:https://doi.org/10.1016/j.colsurfa.2022.129138.